Title
Triangular Shaped Graphene-Ag3PO4 Hybrid Nanocomposite: An Efficient Photocatalyst for the Degradation of Phenol under Visible Light Irradiation
Authors
Sanjay R. Thakare,*a Sandeep B. Gawande,b Kalpana B. Gawandea and Vivek R. Matec
aDepartment of Chemistry, Government Institute of Forensic Science, Civil Lines, Nagpur, 440001, India.
bChemical Laboratory, Mineral Exploration Corporation Limited, Nagpur, 440006, India.
cDepartment of Chemistry, Y.C. Arts and Science College, Mangrulpir, Washim, 444405, India.
*Corresponding author E-mail address: sanjaythakare@yahoo.co.uk (S.R. Thakare)
Article History
Publication details: Received: 21st June 2020; Revised: 09th July 2020; Accepted: 10th July 2020; Published: 14th July 2020
Cite this article
Sanjay R. T.; Sandeep B. G.; Kalpana B. G.; Vivek R. M. Triangular Shaped Graphene-Ag3PO4 Hybrid Nanocomposite: An Efficient Photocatalyst for the Degradation of Phenol under Visible Light Irradiation. Nano Prog., 2020, 2(4), 1-6.
Abstract
Graphene-Ag3PO4 hybrid nanocomposite with the unique triangular morphology of Ag3PO4 is successfully fabricated by simple one pot hydrothermal method. The hybrid Graphene-Ag3PO4 nanocomposite photocatalyst was characterized by different advanced analytical instruments for morphological and physiochemical properties of material. The results are promising and nano Graphene-Ag3PO4 hybrid composite shows improved photocatalytic movement than pure Ag3PO4 for degradation of phenol. SEM shows the in-situ growth of finely distributed triangular shaped Ag3PO4 nanoparticles over the surface of graphene sheets. Production of .OH radicals on the Ag3PO4 surface was detected by the PL technique applying coumarin as an investigating chemical. The effect of graphene (from 10 to 50 wt %) loading in composite material on rates of degradation of phenol in aqueous solution was investigated. Among prepared catalysts an optimum 20 wt% graphene loading in hybrid nanocomposite visible light catalyst shown two times higher activity than pure Ag3PO4, further loading of graphene lowers activity.
Keywords
Ag3PO4; Graphene-Ag3PO4 nanocomposite; Phenol; Photocatalytic degradation